Sequentially sampled gas hydrate water,coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano,Lake Baikal: ambiguous deep-rooted source of hydrate-forming water     

Hirotsugu Minami  Akihiro Hachikubo  Hirotoshi Sakagami  Satoshi Yamashita  Yusuke Soramoto  Tsuyoshi Kotake  Nobuo Takahashi  Hitoshi Shoji  Tatyana Pogodaeva  Oleg Khlystov  Andrey Khabuev  Lieven Naudts  Marc De Batist 《Geo-Marine Letters》2014,34(2-3):241-251

The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl^– and HCO₃ ^– remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl^– concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO₃ ^– concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO₃ ^–/Cl^– ratio of 305 differed markedly from downcore pore water HCO₃ ^–/Cl^– ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ¹⁸O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ¹⁸O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ¹⁸O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.  相似文献   

High-Resolution Analysis of Debris Flow–Induced Channel Changes in a Headwater Stream,Ashio Mountains,Japan∗     

Thad A. Wasklewicz  Tsuyoshi Hattanji 《The Professional geographer》2013,65(2):231-249

Coupled hillslope and channel processes in headwater streams (HWS) lead to rapid changes in channel dimensions. Changes in channel size and shape caused by a debris flow event along the length of a headwater stream in the Ashio Mountains, Japan, were captured with the aid of repeat high-definition surveys using terrestrial laser scanning (TLS) techniques. The HWS was classified into three distinct reaches below the debris flow initiation zone. A large knickpoint separated an upper bedrock reach from a colluvial reach along the midsection of the drainage. The colluvial reach transitioned to a lower bedrock reach that terminated at the master stream. Cross-sectional and morphometric analyses revealed no statistically significant changes in channel size or shape along the upper bedrock reach. Debris flow erosion generated significant differences in channel size and shape along a colluvial reach. Sediment bulking associated with erosion along the colluvial reach led to increases in channel size along the lower bedrock reach, but no statistical differences in channel shape. Morphometric analyses from the TLS point cloud revealed that debris flow erosion produced a distinct nonlinear change in channel dimensions in the downstream direction within the HWS. Variations in channel substrate along the length of HWS contributed directly to this nonlinear response. The episodic nature and nonlinearity of erosion associated with the current debris flow event highlights the importance of debris flows in general in understanding the transport of sediment, coarse to fine particulate organic material, and large woody debris, which are critical to the long-term management of riverine environments. TLS sampling methods show promise as one component of a multianalytical approach needed to continuously monitor and manage the dynamics of HWS.  相似文献   

Four-dimensional variational ocean reanalysis: a 30-year high-resolution dataset in the western North Pacific (FORA-WNP30)     

Norihisa Usui  Tsuyoshi Wakamatsu  Yusuke Tanaka  Nariaki Hirose  Takahiro Toyoda  Shiro Nishikawa  Yosuke Fujii  Yasushi Takatsuki  Hiromichi Igarashi  Haruka Nishikawa  Yoichi Ishikawa  Tsurane Kuragano  Masafumi Kamachi 《Journal of Oceanography》2017,73(2):205-233

We produced a four-dimensional variational ocean re-analysis for the Western North Pacific over 30 years (FORA-WNP30). It is the first-ever dataset covering the western North Pacific over 3 decades at eddy-resolving resolution. The four-dimensional variational analysis scheme version of the Meteorological Research Institute Multivariate Ocean Variational Estimation system (MOVE-4DVAR) is employed to conduct a long-term reanalysis experiment during 1982–2012. After evaluating the basic performance of FORA-WNP30, the interannual to decadal variability is analyzed. Overall, FORA-WNP30 reproduces basic features in the western North Pacific well. One of outstanding features in FORA-WNP30 is that anomalous events such as the Kuroshio large meander and anomalous intrusion of the Oyashio in the 1980s, when there were no altimeter data, are successfully reproduced. FORA-WNP30 is therefore a valuable dataset for a variety of oceanographic research topics and potentially for related fields such as climate study, meteorology and fisheries.  相似文献   

Phylogeny and phylogeography of the land hermit crab Coenobita purpureus (Decapoda: Anomura: Coenobitidae) in the Northwestern Pacific Region          下载免费PDF全文

Katsuyuki Hamasaki  Chikako Iizuka  Tetsuya Sanda  Hideyuki Imai  Shuichi Kitada 《Marine Ecology》2017,38(1)

Hermit crabs of the family Coenobitidae comprise the land hermit crabs, with 16 Coenobita species, and the coconut crab Birgus latro. They are terrestrial but spend their marine life as planktonic larvae. Some coenobitid crabs are widely distributed in the Indo‐West Pacific region, and some species occupy narrower ranges. To improve our knowledge of coenobitid crab speciation and geographical distribution patterns, we examined the phylogenetic relationship between Coenobita purpureus, which has a narrow distribution in the Northwestern Pacific, and its more widely distributed coenobitids including B. latro, Coenobita brevimanus, Coenobita cavipes, Coenobita perlatus, Coenobita rugosus and Coenobita violascens based on the mtDNA cytochrome c oxidase subunit I (COI) and 16S rDNA genes. We also assessed the phylogeography of Co. purpureus populations based on the COI gene. Our phylogenetic and phylogeographical analyses revealed that (i) Co. purpureus clustered with Co. rugosus and (ii) the Co. purpureus population in the Ogasawara Islands was genetically distinct from those in other regions, which showed genetic panmixia. It has been hypothesized that Co. purpureus evolved in the isolated landmasses of the Ryukyu region during the Pliocene, and that its population expanded and colonized the Ogasawara Islands in the late Pleistocene. Further phylogeographical studies on Coenobita species with relatively narrow distributions coupled with characterization of their phylogenetic relationships with widely distributed congeners will advance our knowledge of the speciation and geographical distribution history of coenobitid crabs.  相似文献   

Horizontal distribution of calanoid copepods in the western Arctic Ocean during the summer of 2008   总被引：1，自引：1，他引：0  

Kohei Matsuno  Atsushi Yamaguchi  Koji Shimada  Ichiro Imai 《Polar Science》2012,6(1):105-119

The horizontal distribution of the epipelagic zooplankton communities in the western Arctic Ocean was studied during August–October 2008. Zooplankton abundance and biomass were higher in the Chukchi Sea, and ranged from 3,000 to 274,000 ind. m^?2 and 5–678 g WM m^?2, respectively. Copepods were the most dominant taxa and comprised 37?94% of zooplankton abundance. For calanoid copepods, 30 species belonging to 20 genera were identified. Based on the copepod abundance, their communities were classified into three groups using a cluster analysis. The horizontal distribution of each group was well synchronized with depth zones, defined here as Shelf, Slope and Basin. Neritic Pacific copepods were the dominant species in the Shelf zone. Arctic copepods were substantially greater in the Slope zone than the other regions. Mesopelagic copepods were greater in the Basin zone than the other regions. Stage compositions of large-sized Arctic copepods (Calanus glacialis and Metridia longa) were characterized by the dominance of late copepodid stages in the Basin. Both the abundance and stage compositions of large copepods corresponded well with Chl. a concentrations in each region, with high Chl. a in the Shelf and Slope supporting reproduction of copepods resulting in high abundance dominated by early copepodid stages.  相似文献   

Geology and Skarn Cu–Bi–Au Mineralization at Shwe Min Bon Area,Kalaw Township,Southern Shan State,Myanmar     

Nyein N. Sint  Kotaro Yonezu  Thomas Tindell  May T. Aye  Htay Win  Akira Imai  Koichiro Watanabe 《Resource Geology》2019,69(1):85-106

The Shwe Min Bon Cu–Au skarn deposit lies within one of the largest Au–Cu belts in Myanmar. The deposit is situated along the Shan scarp zone, which marks the boundary between the Myanmar central basin to the west and the Shan plateau to the east. The Shwe Min Bon deposit comprises skarn‐type metasomatic alteration, and the Cu–Au mineralization occurs along the contact face between the Nwabangyi Dolomite and Shweminbon Formation and the Cretaceous dioritic rocks. The metasomatic process resulted in pro‐ and retrograde mineral assemblages in exoskarn. Hydrothermal activities in the Shwe Min Bon deposit are classified into prograde, retrograde stage I, and retrograde stage II. The prograde skarn is classified into a proximal garnet skarn with minor clinopyroxene and a distal wollastonite skarn. Chlorite, epidote, and tremolite–actinolite were formed during the retrograde stage I. Cu–Au mineralization mainly occurred in retrograde stage I, which was characterized by moderate temperatures (260–320 °C) and fluid with a moderate salinity (5.0–6.0% NaCl equiv.). Low temperature (180–200 °C) and low salinity (2.0–3.0% NaCl equiv.) were responsible for retrograde stage II. Au mineralization is mainly associated with chalcopyrite and tennantite in retrograde stage I and with tellurobismuthite in retrograde stage II.  相似文献   

Geology,Alteration, and Mineralization of the Kay Tanda Epithermal Gold Deposit,Lobo, Batangas,Philippines     

Sofia Marah P. Frias  Akira Imai  Ryohei Takahashi  Ma. Ines Rosana Balangue‐Tarriela  Carlo Arcilla  Nigel Blamey 《Resource Geology》2019,69(4):351-384

The Kay Tanda epithermal Au deposit in Lobo, Batangas is one of the Au deposits situated in the Batangas Mineral District in southern Luzon, Philippines. This study aims to document the geological, alteration, and mineralization characteristics and to determine the age of the mineralization, the mechanism of ore deposition, and the hydrothermal fluid characteristics of the Kay Tanda deposit. The geology of Kay Tanda consists of (i) the Talahib Volcanic Sequence, a Middle Miocene dacitic to andesitic volcaniclastic sequence that served as the host rock of the mineralization; (ii) the Balibago Diorite Complex, a cogenetic intrusive complex intruding the Talahib Volcanic Sequence; (iii) the Calatagan Formation, a Late Miocene to Early Pliocene volcanosedimentary formation unconformably overlying the Talahib Volcanic Sequence; (iv) the Dacite Porphyry Intrusives, which intruded the older lithological units; and (v) the Balibago Andesite, a Pliocene postmineralization volcaniclastic unit. K‐Ar dating on illite collected from the alteration haloes around quartz veins demonstrated that the age of mineralization is around 5.9 ± 0.2 to 5.5 ± 0.2 Ma (Late Miocene). Two main styles of mineralization are identified in Kay Tanda. The first style is an early‐stage extensive epithermal mineralization characterized by stratabound Au‐Ag‐bearing quartz stockworks hosted at the shallower levels of the Talahib Volcanic Sequence. The second style is a late‐stage base metal (Zn, Pb, and Cu) epithermal mineralization with local bonanza‐grade Au mineralization hosted in veins and hydrothermal breccias that are intersected at deeper levels of the Talahib Volcanic Sequence and at the shallower levels of the Balibago Intrusive Complex. Paragenetic studies on the mineralization in Kay Tanda defined six stages of mineralization; the first two belong to the first mineralization style, while the last four belong to the second mineralization style. Stage 1 is composed of quartz ± pyrophyllite ± dickite/kaolinite ± diaspore alteration, which is cut by quartz veins. Stage 2 is composed of Au‐Ag‐bearing quartz stockworks associated with pervasive illite ± quartz ± smectite ± kaolinite alteration. Stage 3 is composed of carbonate veins with minor base metal sulfides. Stage 4 is composed of quartz ± adularia ± calcite veins and hydrothermal breccias, hosting the main base metal and bonanza‐grade Au mineralization, and is associated with chlorite‐illite‐quartz alteration. Stage 5 is composed of epidote‐carbonate veins associated with epidote‐calcite‐chlorite alteration. Stage 6 is composed of anhydrite‐gypsum veins with minor base metal mineralization. The alteration assemblage of the deposit evolved from an acidic mineral assemblage caused by the condensation of magmatic volatiles from the Balibago Intrusive Complex into the groundwater to a slightly acidic mineral assemblage caused by the interaction of the host rocks and the circulating hydrothermal waters being heated up by the Dacite Porphyry Intrusives to a near‐neutral pH toward the later parts of the mineralization. Fluid inclusion microthermometry indicates that the temperature of the system started to increase during Stage 1 (T = 220–250°C) and remained at high temperatures (T = 250–290°C) toward Stage 6 due to the continuous intrusion of Dacite Porphyry Intrusives at depth. Salinity slightly decreased toward the later stages due to the contribution of more meteoric waters into the hydrothermal system. Boiling is considered the main mechanism of ore deposition based on the occurrence of rhombic adularia, the heterogeneous trapping of fluid inclusions of variable liquid–vapor ratios, the distribution of homogenization temperatures, and the gas ratios obtained from the quantitative fluid inclusion gas analysis of quartz. Ore mineral assemblage and sulfur fugacity determined from the FeS content of sphalerite at temperatures estimated by fluid inclusion microthermometry indicate that the base metal mineralization at Kay Tanda evolved from a high sulfidation to an intermediate sulfidation condition.  相似文献   

Sequential Chemical Separation of Cr and Ti from a Single Digest for High‐Precision Isotope Measurements of Planetary Materials     

Yuki Hibiya  Tsuyoshi Iizuka  Katsuyuki Yamashita  Shigekazu Yoneda  Akane Yamakawa 《Geostandards and Geoanalytical Research》2019,43(1):133-145

Combined determination of Cr and Ti isotopes of planetary materials offers a means with which to investigate their genetic relationship and the evolution of the protoplanetary disk. Here, we report the new sequential chemical separation procedure for combined Cr and Ti isotope ratio measurements. It comprises three steps: (a) Fe removal using AG1‐X8 anion exchange resin, (b) Ti separation using TODGA resin and (c) Cr separation using AG50W‐X8 cation exchange resin (with one additional step of Ti purification using AG1‐X8 anion exchange resin for samples having high Cr/Ti and Ca/Ti ratios). We applied the proposed procedure to terrestrial and meteorite samples with various compositions. Typical recovery rates of 90–100% were achieved with total procedural Cr and Ti blanks of 3–5 and 2–3 ng, respectively. We measured the Cr and Ti isotope compositions of the separated samples using thermal ionisation mass spectrometry and multiple collector‐inductively coupled plasma‐mass spectrometry, respectively. Our Cr and Ti isotope data were found to be consistent with those of previous studies of individual Cr and Ti isotopic compositions of the meteorites. These results demonstrate the capability of our separation method when applied to combined high‐precision Cr and Ti isotope analyses for single digests of planetary materials.  相似文献   

Monitoring of DSP toxins in small-sized plankton fraction of seawater collected in Mutsu Bay,Japan, by ELISA method: relation with toxin contamination of scallop     

Imai I  Sugioka H  Nishitani G  Mitsuya T  Hamano Y 《Marine pollution bulletin》2003,47(1-6):114-117

Monitorings were conducted on DSP toxins in mid-gut gland of scallop (mouse assay), cell numbers of toxic dinoflagellate species of Dinophysis, and diarrhetic shellfish poisoning (DSP) toxins in small-sized (0.7-5 microm) plankton fraction of seawater collected from surface (0 m) and 20 m depth at a station in Mutsu Bay, Aomori Prefecture, Japan, in 2000. A specific enzyme-linked immunosorbent assay (ELISA) was employed for the analysis of DSP toxins in small-sized plankton fraction using a mouse monoclonal anti-okadaic acid antibody which recognizes okadaic acid, dinophysistoxin-1, and dinophysistoxin-3. DSP toxins were detected twice in the mid-gut gland of scallops at 1.1-2.3 MU (mouse units) g(-1) on 26 June and at 0.6-1.2 MU g(-1) on 3 July, respectively. Relatively high cell densities of D. fortii were observed on 26 June and 11 September, and may only contribute to the bivalve toxicity during late June to early July. D. acuminata did not appear to be responsible for the toxicity of scallops in Mutsu Bay in 2000. ELISA monitoring of small-sized plankton fraction in seawater could detect DSP toxins two weeks before the detection of the toxin in scallops, and could do so two weeks after the loss of the bivalve toxicity by mouse assay. On 17 July, toxic D. fortii was detected at only small number, <10 cells l(-1), but DSP toxins were detected by the ELISA assay, suggesting a presence of other toxic small-sized plankton in seawater. For the purpose of reducing negative impacts of DSP occurrences, monitorings have been carried out hitherto on DSP toxins of bivalve tissues by mouse assay and on cell densities of "toxic" species of Dinophysis. Here we propose a usefulness of ELISA monitoring of plankton toxicity, especially in small-sized fraction, which are possible foods of mixotrophic Dinophysis, as a practical tool for detecting and predicting DSPs in coastal areas of fisheries grounds of bivalve aquaculture.  相似文献   

The Antarctic achondrite ALHA 76005: a polymict eucrite     

Lawrence Grossman  Edward Olsen  Andrew M. Davis  Tsuyoshi Tanaka  Glenn J. MacPherson 《Geochimica et cosmochimica acta》1981,45(8):1267-1279

ALHA 76005 is a basaltic achondrite containing few. if any, orthopyroxenes. Its bulk major and trace element composition is like that of a non-cumulate eucrite, and unlike that of a howardite. It contains a variety of igneous clasts which differ in their textures, pyroxene/plagioclase ratios and pyroxene and plagioclase compositions. One clast, No. 4, was found to have the REE pattern of a cumulate eucrite and an oxygen isotopic composition different from that of the bulk meteorite. Both the chemical and oxygen isotopic composition of clast No. 4 suggest that it was derived from a source different from its host. These observations lead to the conclusion that ALHA 76005 is a polymict eucrite.  相似文献